Ethylenediaminium hemioxalate thiocyanate
نویسندگان
چکیده
In the title compound, C(2)H(10)N(2) (2+)·0.5(C(2)O(4))(2-)·NCS(-), the ethyl-enediaminium dication adopts a (+)-synclinal conformation with an N-C-C-N torsion angle of 62.64 (15)°. The oxalate dianion lies across an inversion centre. In the crystal structure, the ions are linked through N-H⋯N, N-H⋯O and C-H⋯S hydrogen bonds, leading to the formation of a three-dimensional network.
منابع مشابه
Dicyclohexylammonium thiocyanate
In the crystal structure of the title compound, C(12)H(24)N(+)·NCS(-), the anions and cations are linked through N-H⋯N and N-H⋯S hydrogen bonds, resulting in a chain along the a axis.
متن کاملDiisopropylammonium thiocyanate
In the title mol-ecular salt, C(6)H(16)N(+)·NCS(-), the cation possesses approximate local twofold rotation symmetry. One of its NH atoms forms a hydrogen bond to a thio-cyanate N atom and the other to a thio-cyanate S atom. This results in [001] chains of alternating cations and anions.
متن کامل2-Methylbenzimidazolium thiocyanate–2-methylbenzimidazole (1/1)
In the crystal structure of the title compound, C(8)H(9)N(2) (+)·SCN(-)·C(8)H(8)N(2), the three components are linked by inter-molecular N-H⋯N and N-H⋯S hydrogen bonds into infinite chains along the c axis.
متن کاملFred Ward for the preparation of intermediates . Spnthesis and Analgetic Activity of Some 1 - Substituted 3 - Pyrrolidinylanilides and Dihydrobenzoxazinones
3,4,5,6-Tetrahydro-1[2-(4-hydroxy-4-phenyl-l-piperidyl)ethyl] -l-benzazocin-2( 1H)-one Hydrochloride (21).-To 10.0 g (0.057 mole) of 3,4,5,6-tetrahydrobenzazocin-2( lH)-one in 100 ml of xylene was carefully added 3.0 g of NaH with stirring. The reaction mixture was then refluxed with stirring for 2 hr. To the mixture was added 3.0 g of NaH and 19.2 g (0.06 mole) of 1-(2-chlorethyl)-4-hydroxy-4-...
متن کاملCrystal structure of 3-carbamothioylpyridinium thiocyanate
In the cation of the title salt, C6H7N2S(+)·SCN(-), the C=S bond is oriented trans with respect to the C-C=N fragment in the pyridine ring. The planes of the aromatic ring and the thio-amide fragment of the cation make a dihedral angle of 38.31 (4)°. In the crystal, the components are linked by N-H⋯S and N-H⋯N, hydrogen bonds, forming a two-dimensional network parallel to (10-1).
متن کامل